A sample contains 1.0×1020 atoms of isotope A, which decays to isotope B with a half-life of 5 hours. Isotope B decays to stable isotope C with a half-life of 3 hours. Initially, there is no B or C. Find (a) the number of A atoms remaining after 15 hours, (b) the activity of A after 15 hours, (c) the maximum number of B atoms present at any time, and (d) the approximate time at which B reaches its maximum.
Solution:
(a) A atoms remaining after 15 hours:
Number of half-lives of A: n=15/5=3
NA=N0×(21)3=1.0×1020×81=1.25×1019
(b) Activity of A after 15 hours:
λA=t1/2ln2=5×36000.693=3.85×10−5 s−1
A=λANA=3.85×10−5×1.25×1019=4.81×1014 Bq
(c) Maximum number of B atoms:
For a decay chain A → B → C, the number of B atoms is:
Key misconception: Activity =λN (current number of atoms), NOT λN0 (original number). Many students use N0 instead of N after time has passed. Also, half-life is a statistical property — it applies to large numbers of atoms, not to individual atoms.
(a) Calculate the binding energy per nucleon of 56Fe. (b) Calculate the binding energy per nucleon of 235U. (c) For the fission reaction 235U+n→141Ba+92Kr+3nCalculate the energy released.
Solution:
(a) Binding energy of 56Fe:
56Fe has Z=26 protons and N=30 neutrons.
Mass of constituent nucleons:
mnucleons=26×1.00728+30×1.00867=26.18928+30.26010=56.44938 u
Mass defect:
Δm=56.44938−55.93494=0.51444 u
Binding energy:
BE=0.51444×931.5=479.2 MeV
Binding energy per nucleon:
ABE=56479.2=8.557 MeV/nucleon
(b) Binding energy of 235U:
Z=92, N=143.
mnucleons=92×1.00728+143×1.00867=92.66976+144.23981=236.90957 u
Δm=236.90957−235.04393=1.86564 u
BE=1.86564×931.5=1738.1 MeV
ABE=2351738.1=7.396 MeV/nucleon
(c) Energy released in fission:
Reactants: 235U+n=235.04393+1.00867=236.05260 u
Products: 141Ba+92Kr+3n=140.91390+91.92620+3(1.00867)=140.91390+91.92620+3.02601=235.86611 u
Mass defect:
Δm=236.05260−235.86611=0.18649 u
Energy released:
E=0.18649×931.5=173.7 MeV
Key insight: Iron-56 has the highest binding energy per nucleon of any nucleus, making it the most stable. Energy is released both by fission of heavy nuclei (like U-235, moving toward Fe-56) and by fusion of light nuclei (moving toward Fe-56). The BE/A curve peaks at Fe-56.
A piece of ancient wood has a 14C activity of 2.5 decays per minute per gram. Living wood has a 14C activity of 15.3 decays per minute per gram. The half-life of 14C is 5730 years. (a) Calculate the age of the wood. (b) If the measurement uncertainty in activity is ±0.3 decays/min/g, what is the uncertainty in the age? (c) What percentage of the original 14C remains?
Uncertainty: approximately ±1000 years (asymmetric: −933 to +1066).
(c) Percentage remaining:
N0N=A0A=0.1634=16.34%
Key insight: Carbon dating becomes increasingly inaccurate for older samples because the remaining activity approaches the background radiation level. For samples older than about 50000 years (∼9 half-lives), less than 0.2% of the original 14C remains, making reliable dating nearly impossible.
A nuclear power station uses 235U as fuel. Each fission of 235U releases approximately 200 MeV of energy. The power station has a thermal efficiency of 33% and produces 500 MW of electrical power. (a) Calculate the number of 235U fissions per second. (b) The fuel is enriched to 3%235U (the rest is 238U). Calculate the mass of uranium fuel consumed per day. (c) If the waste heat is discharged into a river with a flow rate of 500 m3 s−1Calculate the temperature rise of the river.
Solution:
(a) Fissions per second:
Thermal power output:
Pthermal=ηPelectrical=0.33500×106=1.515×109 W
Energy per fission: E=200 MeV=200×106×1.6×10−19=3.2×10−11 J
Fissions per second=3.2×10−111.515×109=4.734×1019 s−1
Key insight: Nuclear power stations have relatively low thermal efficiency (30—35%), meaning about two-thirds of the energy is waste heat. This is a significant environmental consideration for power station siting.
IT-2: Alpha and Beta Decay with Energy and Momentum Conservation (with Mechanics)
A stationary 226Ra nucleus undergoes alpha decay to 222Rn. The kinetic energy of the alpha particle is 4.78 MeV. (a) Calculate the recoil kinetic energy of the 222Rn nucleus. (b) Calculate the total energy released in the decay. (c) Explain why the alpha particle carries most of the kinetic energy.
Solution:
(a) Recoil energy of 222Rn:
By conservation of momentum (initial momentum =0):
pα=−pRn
mαvα=mRnvRn
Kinetic energies:
KEα=2mαp2,KERn=2mRnp2
KEαKERn=mRnmα=2224=0.01802
KERn=4.78×0.01802=0.0861 MeV
(b) Total energy released:
Q=KEα+KERn=4.78+0.0861=4.866 MeV
(c) Why the alpha particle carries most KE:
Since KE∝1/m for the same momentum, the lighter particle (alpha, mass 4 u) carries much more kinetic energy than the heavier daughter nucleus (Rn, mass 222 u). The ratio is inversely proportional to the mass ratio:
KERnKEα=mαmRn=4222=55.5
The alpha particle carries about 98.2% of the total kinetic energy released.
Key insight: In alpha decay, both energy AND momentum must be conserved. The lighter alpha particle gets most of the kinetic energy. This is analogous to a gun recoiling when fired — the bullet gets much more KE than the gun, even though they have equal and opposite momenta.
IT-3: E = mc^2 Applied to Particle Annihilation (with Electricity and Magnetism)
A positron (e+) and an electron (e−) annihilate, producing two gamma-ray photons. (a) Explain why two photons (not one) are produced. (b) Calculate the wavelength of each photon, assuming the particles are essentially at rest. (c) If the positron has a kinetic energy of 0.5 MeV before annihilation, calculate the new photon wavelength. (d) In a PET scanner, these photons are detected. Explain how the detection of two photons allows localization of the annihilation event.
Solution:
(a) Why two photons:
Conservation of momentum: if the electron and positron are at rest (or nearly so), their total momentum is zero. A single photon always carries momentum (p=E/c), so producing one photon would violate momentum conservation. Two photons travelling in opposite directions can have zero total momentum while carrying away all the energy.
(b) Photon wavelength (particles at rest):
Rest mass energy of electron (or positron): E0=mec2=0.511 MeV
Total energy available: 2×0.511=1.022 MeV
Each photon gets half: Eγ=0.511 MeV =0.511×106×1.6×10−19=8.176×10−14 J
The extra kinetic energy produces shorter-wavelength (higher-energy) photons.
(d) PET scanner localization:
The two photons are emitted in exactly opposite directions (back-to-back, 180° apart). A ring of detectors surrounds the patient. When two detectors fire simultaneously (within a very short coincidence time window), the annihilation event must have occurred somewhere along the line connecting the two detectors. By recording many such coincidence events from multiple angles, a computer reconstructs the 3D distribution of the positron-emitting tracer using tomographic algorithms.
Key insight: Mass-energy equivalence (E=mc2) is not just theoretical — it is the operating principle of PET scanners, one of the most important medical imaging technologies. The complete conversion of mass to energy is the most efficient energy release possible.
Confusing mass number with atomic mass: Mass number is the total count of protons and neutrons (integer). Atomic mass is the actual mass in unified atomic mass units (not necessarily an integer). Don’t round atomic mass to get mass number.
Assuming half-life means half the sample decays in that time: Half-life is the time for HALF the remaining atoms to decay. After one half-life, 50% remains; after two, 25%; after three, 12.5%. It’s exponential decay, not linear.
Mixing up alpha, beta, and gamma radiation properties: Alpha is largest/heaviest (stopped by paper), beta is medium (stopped by aluminium), gamma is smallest (requires thick lead). Don’t confuse their penetrating power or ionising ability.